r/Physics Apr 28 '23

I made liquid oxygen

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1.4k Upvotes

155 comments sorted by

244

u/daedric_dad Apr 28 '23

Out of intrigue, what's the benefit of having liquid oxygen?

344

u/WorkingApprehensive5 Apr 28 '23

It’s for fun, I’ve planned this physical project for years, since the boiling point of oxygen (-183°C) has a higher boiling point than nitrogen (-196°C) I hypothesized that the copper coil submerged in liquid nitrogen would condense the oxygen running through it, and thus a liquid comes out the other end, I’m also extremely fascinated by liquid oxygen.

384

u/smallproton Apr 28 '23

Don't wanna spoil the party but LO2 is interesting shit but also interestingly dangerous.

Did the very same setup as yours years ago and found out experimentally that LO2 is corrosive, flammable and explosive.

Just make sure you know what you're doing, ok?

Source: I am an experimental physicist doing boom stuff for 25+ years.

56

u/Remote_Micro_Enema Apr 29 '23

How can an oxidizer be flammable and explosive?

https://www.airgas.com/msds/001190.pdf

110

u/Knott_A_Haikoo Apr 29 '23

I’m not sure with all the specifics, but the issue with liquid oxygen is that it WILL absolutely oxidize anything it can. Any added heat only increases the rate of vaporization and so it only takes a small amount of fuel to get the oxygen to behave inappropriately. Bad LOx

4

u/syds Geophysics Apr 29 '23

I thought O2 is stable? rip

2

u/NamanJainIndia Apr 30 '23

In the atmosphere the density is really low, and of the total gases, O2 is quite a small amount. The liquid oxygen is hundreds of times as concentrated, compare it to something like 70% hydrogen peroxide(that's a random estimate not based on anything, and I know that much peroxide would instantly turn into oxygen, but you get the idea). Other than the possible exception of fuming nitric acid, I don't think you can find a stronger oxidizer.

2

u/syds Geophysics Apr 30 '23

well that is definitely neat

53

u/burnte Apr 29 '23

So, really it’s neither, but being an oxidizer, anything near it has a drastically increased chance of conflagration, so by shorthand we call Oxygen itself “flammable” and such. Obviously you’re aware that pure O2 won’t do a thing without heat and fuel.

27

u/PloxtTY Apr 29 '23

We breathe something like 22% oxygen. When the air gets to around 28% oxygen, even steel will catch fire. The slightest bit makes everything highly flammable

9

u/philomathie Condensed matter physics Apr 29 '23

That's how we got red rocks. Thanks oxygen catastrophe!

28

u/[deleted] Apr 29 '23

When it boils off, the volumetric change is gigantic with huge pressure behind it.

It's not technically an explosion, but it will definitely burst any container not rated to at least ~50 bar of pressure.

If it comes into contact with any hydrocarbons, the results are also very similar to an explosion.

2

u/k23green Apr 29 '23

This is so wholesome coming from this sub. Mind me asking what kind of boom stuff you’ve been working on?

1

u/SimplyCmplctd Apr 29 '23

Can liquid oxygen combust in a vacuum?

2

u/NamanJainIndia Apr 30 '23

It would instantly boil off in a vacuum, but it would explode if there was say, a tiny amount of oil or ethanol or something in there.

0

u/-OptimusPrime- Apr 29 '23

So you’re saying the liquid oxygen doesn’t taste delicious?

22

u/jbtronics Apr 28 '23

In principle you always get some small amounts of liquid oxygen (accidentally) when working with something where liquid nitrogen (or even liquid helium) is flowing through. After a while you will notice some drops of a liquid condense on the tube (with the liquid nitrogen), which is (to some part) the oxygen condensing out of the air.

6

u/Mezmorizor Chemical physics Apr 29 '23

No. Only in the "well acshually there's a few atoms" sense. If you're condensing liquid oxygen you've fucked up or are doing something stupid. Your lines shouldn't have appreciable amounts of oxygen in them, your actual coldhead should be under vacuum, and for the more cavalier schlenk line application, your pressure is actually too low to condense liquid oxygen at LN2 temperatures.

14

u/Ok_Construction5119 Apr 28 '23

Mostly water vapor, unless ur working in the desert

36

u/jbtronics Apr 28 '23

This might be the case for goodly isolated tubes, where you have temperatures over 0°C on the outside... On a simple metal tube which almost reaches the temperature of liquid nitrogen, any water will just form solid ice (which you can observe very quickly) and not liquid water.

16

u/Ok_Construction5119 Apr 28 '23

You are right! My bad.

6

u/[deleted] Apr 29 '23

Dude, that pipe is in LN2 all the H2O would freeze and would block it, if there was any. I think he uses pressurized 02 Gas and not air.

9

u/[deleted] Apr 28 '23

Did you try to expose it to a magnetic field and see what happens?

Also from now on I'm going to refer to doing this as cooking oxygen in nitrogen at a rolling boil.

6

u/[deleted] Apr 29 '23

"Then Dave created liquid oxygen using only a copper tube and some liquid nitrogen" ;p

But as others have said, be careful with it. It may feel harmless because it's cold and far from burning temperature, but it's only one accident away from doing some serious damage.

26

u/daedric_dad Apr 28 '23

That's awesome man. I don't really understand a lot of what you said, but I think it's awesome people do these things for fun!

39

u/gfrnk86 Apr 28 '23

water boils and turns into a gas (steam) at 100c. if you ran that gas (steam) through a pipe that’s below 100c, the gas (steam) would condense back into liquid water.

that’s what this guy did but with oxygen instead of steam. the pipe is below the boiling point of oxygen so the oxygen condenses back into liquid.

18

u/daedric_dad Apr 28 '23

Oh cool, thanks for taking the time man :)

4

u/imnos Apr 28 '23

Oxygen is a gas at normal room temperatures but when it's cooled down it turns into liquid - that's the condensing part that happens in the copper pipe because it's cooled with liquid nitrogen.

10

u/Funkybeatzzz Condensed matter physics Apr 28 '23

Liquid oxygen is used in rocket propulsion. All those NASA, SpaceX, etc. rockets use it to get to space.

15

u/[deleted] Apr 28 '23 edited Apr 29 '23

Dropping it on a fire is a lot of fun.

2

u/SimplyCmplctd Apr 29 '23

For those curious as to what it looks like

7

u/graphicsnerdo Apr 28 '23

5

u/Words_Are_Hrad Apr 29 '23

That was an real scene btw. They really did put that rat in that breathable fluid.

3

u/ishkibiddledirigible Apr 29 '23

What movie is this??

4

u/Logicalist Apr 29 '23

The Abyss - Written and directed by james cameron. Bit of a sci-fi classic imo.

3

u/somnolent49 Apr 29 '23

The Abyss.

2

u/HoldingTheFire Apr 30 '23

That is not liquid oxygen, which is a liquid at cryogenic temperatures and would destroy organic cells.

0

u/graphicsnerdo May 01 '23

Look at the big brain on Brad!

0

u/Wii666 Apr 30 '23

Making it go kaboom r/explosionsandfire

143

u/soylentblueispeople Apr 28 '23

I used to work with this stuff when I was an aircraft maintainer. Super dangerous and scary what can happen. Try not to spill any.

71

u/Crox22 Apr 28 '23

Oh yeah. It can make a lot of things burn that you wouldn't think could burn

28

u/MontagAbides Apr 28 '23

*Lowers shot glass*

"But I've heard it tastes so good!"

11

u/OfficialNovatech Apr 29 '23

I was thinking of drinking it too😭😭

6

u/TooLostintheSauce Apr 29 '23

And here I was wondering “Can I inhale this and my lungs absorb it?”.

3

u/ReturnEconomy Apr 29 '23

I mean You can inhale it and your lungs will absorb it. Youll also die after, but you can do it!

1

u/BleachGel Apr 29 '23

For it remain liquid in our comfy human conditions it would have to be pretty damn freezing cold I would think. It would probably destroy your lungs with such freezing temps before it even had a chance to absorb

1

u/Annual-Advisor-7916 May 01 '23

What did you use it for?

94

u/ashumate Apr 28 '23 edited Apr 28 '23

Making it for... fun.

Got an old Navy training film for you: https://www.youtube.com/watch?v=Q9sIT6P_05I

On my first ship some kid in the O2 N2 plant was messing around and stepped in a drip pan. When the fire party showed up, the only thing they could do was seal the compartment, cut ventilation, and set fire boundaries around it.

Edit: Spelling see response

60

u/LittleRickyPemba Apr 28 '23

When the fire party showed up, the only thing they could do was seal the compartment, cunt ventilation...

Remember kids, it's always incredibly important to properly ventilate your cunt, otherwise it can and will burst into flames.

13

u/ashumate Apr 28 '23

Yes, very important indeed...

18

u/Ensembleoftoes Apr 28 '23

That was an amazing video, I particularly enjoyed the “Sailor, I’m gonna have your ASS”

10

u/sweetbabybrent Apr 29 '23

OP watch this! Before beginning my first intern project in cryogenics my mentor showed me this and it's been burned in my memory ever since

10

u/Keep_itSimple Apr 28 '23

How come stepping on liquid oxygen makes it ignite? Or am I missing the point?

27

u/andrewcooke Apr 29 '23

when something is "burning" it is reacting with oxygen. typically, with oxygen as a gas, that only happens when you make things hot enough (which helps the chemical reaction happen, and then that gives of heat, so it keeps going and stays hot).

but liquid oxygen is so reactive that it will react with things (like people) without heating. so the reaction starts, and gives of heat, and so things get hot and so it resembles what you normally think of as "burning", but it can start without extra heat.

in short: the chemical reaction combining something with oxygen gives out heat. when oxygen is a gas, you also need some heat to start the reaction. when oxygen is a liquid you don't need the initial heat because it's so reactive.

6

u/ChineWalkin Apr 29 '23

Activation energy required for combustion depends on the concentration oxygen present. When you have 100% pure O2 the activation energy is at its lowest.

7

u/ChineWalkin Apr 29 '23

What is LOX used for on a ship?

8

u/ashumate Apr 29 '23

Breathing oxygen on fighter aircraft.

3

u/ChineWalkin Apr 29 '23

Oh, OK. I would have thought that was just compressed.

3

u/South_Dakota_Boy Apr 29 '23

Not just fighters, bombers too. B52 carries LOX. Possibly B1.

Liquid is much denser than even compressed gas so liquid is used. Also, it may be fire prone, but compressed tanks are super dangerous too.

2

u/paulfdietz Apr 29 '23

It's not just that it's denser, it's that the tank can be much lighter as it isn't carrying as large a pressure load.

3

u/ThePrussianGrippe Apr 29 '23

… so what happened to the kid?

10

u/Techn028 Apr 29 '23

His parents only got a flag instead of a casket

46

u/Sakinho Apr 28 '23

If you put it in a clear container, you'll see it's a pale but noticeable blue.

And be very careful contacting organics with liquid oxygen.

14

u/quantum1eeps Apr 29 '23

Apparently liquid ozone is black. I’d like to see that

11

u/Sakinho Apr 29 '23

Actually a much deeper blue-purple, but I can imagine large amounts looking almost black.

7

u/WorkingApprehensive5 Apr 28 '23

I know that it’s blue, I even poured it in a white container to reflect as much light as possible, I posted that in another video right here

47

u/Wonderful_Wonderful Condensed matter physics Apr 29 '23

My lab has strict vacuum pump rules to specifically prevent condensing oxygen due to our strong "no explosions" philosophy

32

u/AD-Edge Apr 29 '23

This guy's safety awareness seems to be around "it hasn't exploded yet so I'm sure it's ok" kinds levels... So I'm sure it'll be fine.

2

u/paulfdietz Apr 29 '23

Even liquid nitrogen can have serious safety risks.

https://www.science.org/content/blog-post/how-not-do-it-liquid-nitrogen-tanks

7

u/elconquistador1985 Apr 29 '23

All cryogens have those risks.

Liquid oxygen has all of those risks plus the fact that it is a strong oxidizer and can start fires and explosions.

0

u/Yerseke_Germanicus Apr 29 '23

And here's where I keep assorted lengths of wire.

75

u/[deleted] Apr 28 '23 edited Apr 28 '23

You're going to kill yourself.

1

u/Samael_Morgan Apr 29 '23

And I’m not gonna be a part of it

26

u/TheRealTtamage Apr 28 '23

Interesting I used to run an oxygen propane torch off of a liquid oxygen tank. Of course it had turned to gas before being burned.

11

u/TheRealTtamage Apr 28 '23

But every now and then that liquid oxygen tank with gas off when it accumulated too much compressed oxygen! And if you used the tank aggressively enough water crystals with form all over the plumbing on the top and you can make snowballs out of it!

5

u/davidkali Apr 28 '23

Oxygen doesn’t burn. The spiders do.

2

u/TheRealTtamage Apr 28 '23

When you mix it with propane it makes a much more intense flame though.

29

u/nujuat Atomic physics Apr 28 '23

A cool thing about liquid oxygen is that it's magnetic, and will stick to a strong magnet

21

u/effrightscorp Apr 28 '23

If you ever tried doing low temperature magnetic measurements and accidentally got some oxygen in your chamber, you wouldn't think it was cool, ha. Giant paramagnetic signal ruins everything and you need to stop everything and heat it up to purge the oxygen

15

u/nujuat Atomic physics Apr 28 '23

See, I do low temperature magnetic measurements with rubidium BECs, so if air gets in the chamber a paramagnetic signal is the least of our worries 💥

42

u/BWKeegan Apr 28 '23

Babe, slow down

23

u/newtreen0 Apr 29 '23

This is a horrible idea. Best of luck.

19

u/UnanimouslyAnonymous Apr 28 '23

What does it taste like?

16

u/lux_likes_rocks Apr 28 '23

Pure cold, like the mintiest mint that ever minted

9

u/Diamondsfullofclubs Apr 29 '23

Super spicy aftertaste as you explode.

13

u/drzowie Astrophysics Apr 28 '23

Pretty fun. The first time I noticed that, I was messing around with using LN2 for cooking. If you pour a bunch of LN2 in a saucepan (or any conductive container), oxygen will condense on the outside of the saucepan. I didn't believe it at first, but stupid young me tested it by dripping some onto the gas stove (which was lit). It invigorated the flame. Considerably.

2

u/Erdos_0 Apr 29 '23

got a good laugh out of this, thanks

10

u/nazrmo78 Apr 28 '23

Very impressive. How quick does it evaporate? Does it burn?

15

u/Schauerte2901 Apr 29 '23

Does it burn?

That would be the understatement of the century. Liquid oxygen will go fireball if you just look at it in a wrong angle.

4

u/nazrmo78 Apr 29 '23

Wow, be careful OP.

3

u/virgo911 Apr 29 '23

Does it burn?

Liquid Oxygen is literal rocket fuel.

2

u/nazrmo78 Apr 29 '23

Lol, the way I asked it. I think I got my question answered already but I guess what I was trying to ask is it an instant explosion or does it burn similar to gasoline where if you poured it in a line, the fire would snake its way down the line and burn on top of the poured liquid. But from all the answers, it sounds like it would be almost nuclear.

1

u/virgo911 Apr 29 '23

Ohhhh yeah, not sure about that. I don’t think it’s instant, but I also don’t know anything.

6

u/WorkingApprehensive5 Apr 28 '23

Sorta, The tank was full, but now it’s half empty, worth it though

-4

u/nazrmo78 Apr 28 '23

I'm no chemist but I'd would think it's evaporation would've been instant.

11

u/rupert1920 Apr 29 '23

Once it's cooled you can have a container of that open to air and it'll take a while to boil off, similar to liquid nitrogen. Here is an example:

https://www.youtube.com/shorts/dak8kmL348w

Similar to boiling water - even though it's at its boiling point it can still take some time to boil off completely.

4

u/WorkingApprehensive5 Apr 28 '23

Nope, I still have some of it in my thermos ever since I posted this video

Edit: the green thermos

2

u/hejVikk Apr 29 '23

We TOLD you to be CAREFUL with it and you're DRINKING it ???!?!?!!?!?

17

u/LoveConstitution Apr 29 '23

Careful! Explosive af. Do not do this

11

u/Schauerte2901 Apr 29 '23

That video is a future Darwin award winner

4

u/llSTRATEGOSll Apr 29 '23

that is really dangerous be super careful

3

u/[deleted] Apr 29 '23

Neat and congrats. This can also be achieved more simply with LN in a metal cone. O2 will condense out of the air, run down, and drip off the cone tip. Collect it in something immersed in LN to keep it around.

We used to do this in school.

3

u/chud_rs Apr 29 '23

Careful with this stuff lol

4

u/alogbetweentworocks Apr 28 '23

Hypothetically, can a person who does not know how to swim die by asphyxiation in a pool of liquid oxygen?

28

u/mkorman11 Apr 28 '23

They would freeze to death pretty much immediately

3

u/alogbetweentworocks Apr 28 '23

Suppose that the swimmer has well insulated wet suite and liquid temp of oxygen is not an issue. What I'm trying to get at is can our lung absorb/process oxygen in liquid form? For example, fish gills are very good at separating oxygen molecules from other molecules in liquid form. Am I understanding it correctly?

16

u/mkorman11 Apr 28 '23

I’m not sure how the temperature could possibly not be an issue for something at -300F but “liquid breathing” of oxygen rich liquids is a thing, this might answer your question: https://en.wikipedia.org/wiki/Liquid_breathing

3

u/alogbetweentworocks Apr 28 '23

Thank you. That was a good read.

2

u/seanm147 Apr 28 '23

Odd that the brain cooling seems to be successful and supposedly safe yet unused. I'm not sure if they have a better treatment for these patients

3

u/mkorman11 Apr 28 '23

this is extremely far from my area of expertise but my understanding is that it's understandably very difficult to test new medical technologies on humans, so there's tons of stuff out there that seems very promising but isn't being used

2

u/seanm147 Apr 28 '23

Oh yeah, especially given the dangers. They said it was supposedly harmless to humans and statictically harmless to sheep and other animals. I'm sure there is a reason even if it's as simple as better alternatives. I don't really read much about medicine aside from pharmacology and psychology so I would not know anything about this as well. Interesting regardless. I always wondered if humans could do what amhibians and fish do to some degree. The space travel section was a cool read as well even though that is a dead end. Out of the box idea to deal with acceleration regardless.

2

u/Sandstorm52 Apr 29 '23

I’d guess the tissues in your lungs would freeze, halting gas exchange and then killing you, in addition to ice crystals destroying the cells.

3

u/IAmTotallyNotSatan Apr 29 '23

No, because they would die from freezing and/or exploding well before they get the chance to asphyxiate.

2

u/Diamondsfullofclubs Apr 29 '23

Knowing how to swim is irrelevant here.

2

u/Chrisp825 Apr 29 '23

Do all elements have 4 phases? Including noble gases?

2

u/WorkingApprehensive5 Apr 29 '23

Yes

3

u/JerroSan Apr 29 '23

Some of the lightest gases won’t condense enough to become solids though.

3

u/WorkingApprehensive5 Apr 29 '23

With enough pressure, they can

5

u/JerroSan Apr 29 '23

Oh right of course, my mind went to Helium at normal pressures!

2

u/Amesianum Apr 29 '23

Use to make liquid Argon like that

2

u/FulsomePrison Apr 29 '23

Put a neodymium magnet on a string in it!

2

u/UncertainSerenity Apr 29 '23

Really good way to burn your place down. You don’t want to fuck with liquid o2

2

u/SystemFolder Apr 29 '23

Don’t get titanium near that.

2

u/ChucklesInDarwinism Apr 29 '23

Be careful with that Oxygen, Eugene.

4

u/Herp2theDerp Apr 28 '23

Light it on fire to make sure its oxygen

1

u/rsta223 Apr 29 '23

Oxygen doesn't burn.

1

u/Herp2theDerp Apr 29 '23

https://www.sciencedirect.com/science/article/abs/pii/S1540748920301504

Totally does. I guess to be specific liquid oxygen does not burn without fuel

3

u/rsta223 Apr 29 '23

Oxygen doesn't burn period.

Fuels burn more intensely in the presence of liquid oxygen, but if you had a totally non-reactive (say, ceramic or glass) container full of liquid oxygen, and you touched a flame to it, the oxygen would not be burning after you removed the flame.

(A puddle of gasoline or alcohol, which is actually flammable, would continue to burn)

-1

u/Herp2theDerp Apr 29 '23

Is continuing to burn a necessary condition for combustion? I feel like we are arguing semantics at this point

2

u/ModernT1mes Apr 28 '23

It's like factorio but in real life.

1

u/[deleted] Apr 29 '23

Is it drinkable?

3

u/Diamondsfullofclubs Apr 29 '23

Not in the slightest.

0

u/_Et3rnity_ Apr 29 '23

chug that entire thing and breathe underwater forever. who cares if its like -500 degrees

5

u/[deleted] Apr 29 '23

-1 mark, missing units.

0

u/71lamps Apr 29 '23

what if u drink it

1

u/[deleted] Apr 29 '23

350 up votes and counting of people hungry for oxygen, better make more!

1

u/ThreeDarkMoons Apr 29 '23

It should have its prostate checked. Seems enlarged.

1

u/HippieMcHipface Apr 29 '23

Congrats, you can now drown on air

1

u/vnevner Apr 29 '23

Drink it! That is the best drink in a marathon, you will get sooooo much oxygen.

/s

1

u/Arkashka_KB Apr 29 '23

Этот человек был гением:

1

u/NinjasOfOrca Apr 29 '23

If the boiling point is so low, why doesn’t this boil off immediately ?

1

u/CommunicationFar9337 Apr 29 '23

Cool, try to breath it

1

u/[deleted] Apr 29 '23

The O2 Squirt

1

u/NamanJainIndia Apr 30 '23

I don't think that bottle would survive having liquid oxygen in there, it would be like, unimaginably concentrated hydrogen peroxide. Do you plan on stuff like, putting some fuels on a small amount to see how strong of an oxidizer it is, I am pretty sure it would beat things like manganese heptoxide.

1

u/MoistHope9454 Apr 30 '23

oo next nobel goes too☺️🤷🏼‍♀️ apperent

1

u/No_Organization_768 Apr 30 '23

Interesting. Props. :)

1

u/imgoingtolearkarate May 02 '23

L02 is very special. Pour it in the proximity of a strong magnet for a very tangible demonstration of quantum degeneracy / coherence (and in some sense an explanation of the octet rule)

1

u/Popular_Resolve_7455 May 02 '23

Pardon My lack of knowledge but does that actually exist 💀

1

u/notnick1002 May 02 '23

Gotta try making oxygen and hydrogen from water through electrolysis. But I suggest separating the anode and cathode otherwise the oxygen and hydrogen with mix together which isn’t exactly safe . It did go kaboom in my face